Preservative-treated
wood is a natural choice for construction projects in our public lands.
Preservative-treated wood is an economical, durable,
andaesthetically pleasing building material; therefore, it is a natural choice
for construction projects in our National Forests, National Parks, and other
public lands. However, we need to ensure that the chemicals used in treated
wood do not pose a threat to people or the environment.
The waterborne wood preservatives chromated copper arsenate (CCA),
ammoniacal copper zinc arsenate (ACZA),ammoniacal copper quat (ACQ), copper
dimethyldithiocarbamate(CDDC), andammoniacal copper citrate (CC) resist leaching during service because of
complex chemical reactions that take place within the treated wood. The
effectiveness of these reactions in preventing leaching is dependent on
treating factors, such as preservative formulation, preservative retention, and
processing techniques, as well as post-treatment conditioning factors, such as
temperature, humidity, and air flow. Copper naphthenate, an oilbornewood
preservative, resists leaching because it is relatively insoluble in water.
Little information is available on the inserviceleaching rates of any of these
wood preservatives, although CCA has been studied more extensively than the other
preservatives.
Past studies report widely varying leaching rates, but
generally agree that the most rapid leaching occurs within the first months of
service and is greatest in products with high retention levels and high proportions
of exposed surface area, especially end-grain. Leaching is also increased by
exposing the wood to high water flow, low pH, and water-soluble organic acids.
Movement of leached chromium and copper appears
quite limited in soil, because the metals are tightly bound to organic soil
constituents.
Arsenic is slightly more mobile in soil, but binds to iron,
aluminum, and manganese. Generally, the preservative components are least
mobile in organic soils, slightly more mobile in clay soils, and most mobile in
sandy soils. In aquatic applications, the leached preservative components form
complexes with the organic sediment fines, and accordingly are either deposited
or moved downstream with the sediments. Additional research is needed to
characterize typical in-service leaching rates of these preservatives and to
determine how processing parameters affect long-term leaching rates.
Lebow, Stan. Leaching of wood preservative components and
their mobility in the environment—Summary of pertinent literature. U.S.
Department of Agriculture, Forest Service, Forest Products Laboratory.
Pressure Treated Wood Preservatives
Pressure Treated Wood Preservatives
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